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Template-Directed Synthesis of a Conjugated Zinc Porphyrin Nanoball

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https://figshare.com/articles/dataset/Template-Directed_Synthesis_of_a_Conjugated_Zinc_Porphyrin_Nanoball/6144566
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We report the template-directed synthesis of a π-conjugated 14-porphyrin nanoball. This structure consists of two intersecting nanorings containing six and 10 porphyrin units. Fluorescence upconversion spectroscopy experiments demonstrate that electronic excitation delocalizes over the whole three-dimensional π system in less than 0.3 ps if the nanoball is bound to its templates or over 2 ps if the nanoball is empty.
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2018-04-16
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