The Elusive <i>closo</i>-Ge<sub>10</sub><sup>2−</sup> Zintl Ion: Finally “Captured” as a Ligand in the Complex [Ge<sub>10</sub>Mn(CO)<sub>4</sub>]<sup>3−</sup>
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Although often seen in mass spectra, the otherwise elusive closo-Ge102− Zintl ion has been finally structurally characterized as coordinated to manganese in [Ge10Mn(CO)4]3− made by the reaction of nido-Ge94− with Mn2(CO)10 in ethylenediamine. The new cluster is a bicapped square antiprism, as expected for a closo-deltahedron of 10 atoms.
创建时间：
2010-07-19
