Synthesis and Structural Characterization of a Fluorinated α-Diimine Platinum(II) Complex
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_a_Fluorinated_-Diimine_Platinum_II_Complex/12068427
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资源简介：
The preparation of an electron-deficient (N−N)PtCl2 complex in which the diimine C is substituted by
CF3 is described. Thus, reactions between the diimine ligand 1 (R = CF3, R‘ = 2,6-dimethylphenyl) and
PtCl2 (thermal reaction) or KPtCl3(C2H4) (photochemically activated) furnishes the corresponding (N−N)PtCl2 complex 2. The ligand 1 and its Pt complexes 2, as well as related (N−N)PtCl2 complexes 3 (R
= CO2CD3, R‘ = 2,6-dimethylphenyl; a methanolysis product) and 4 (R = H, R‘ = 2,6-dimethylphenyl)
have been characterized by X-ray crystallography.
创建时间：
2007-03-26
