Structural characteristics and fluorescence properties of two families of coordination complexes comprised of metal halides and naphthalimide derivatives

Crystallographic information files of all the crystal structures well described in the dissertation titled "Structures and solid-state fluorescence of coordination compounds of metal halides and naphthalimide derivatives".  The complexes are formed from a combination of imnap and CoCl2, CoBr2, CuBr2, ZnBr2, ZnI2, CdBr2, CdI2, HgBr2 or HgI2 and they display a distorted tetrahedral geometry, with no solvent incorporated into the structures. The combination of imnap and CuCl2 results in a complex with a severely distorted tetrahedral geometry. When self-assembled from dimethyl sulfoxide (DMSO), ten new complexes are formed from the combinations of imnap and CoCl2, CuCl2, CuBr2, ZnCl2, ZnBr2, CdCl2, CdBr2, HgCl2, HgBr2 or HgI2, all exhibiting tetrahedral geometries, with DMSO molecules incorporated into the crystal structures.

本数据集收录了收录于名为《金属卤化物和萘酰亚胺衍生物配位化合物的结构和固态荧光》的论文中详尽描述的所有晶体结构的水晶学信息文件。该数据集中的配合物由imnap与CoCl2、CoBr2、CuBr2、ZnBr2、ZnI2、CdBr2、CdI2、HgBr2或HgI2的混合物形成，它们呈现出扭曲的四面体几何结构，结构中未包含溶剂分子。imnap与CuCl2的混合物则产生了严重扭曲的四面体几何结构的配合物。当从二甲基亚砜（DMSO）中自组装时，imnap与CoCl2、CuCl2、CuBr2、ZnCl2、ZnBr2、CdCl2、CdBr2、HgCl2、HgBr2或HgI2的混合物形成了十种新的配合物，所有这些配合物均展现出四面体几何结构，且DMSO分子被纳入晶体结构之中。