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IPr*(2‑Np)An Exceedingly Bulky N‑Heterocyclic Carbene

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/IPr_sup_2_Np_sup_An_Exceedingly_Bulky_N_Heterocyclic_Carbene/2324614
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Does size matter? The bulkiest, yet still highly flexible, N-heterocyclic carbene to date is reported. Its imidazolium salt proved to be easily synthesized in only four steps on a 3.6 g scale. This new ligand was fully characterized and engaged in the formation of complexes with silver­(I), copper­(I), rhodium­(I), and palladium­(II).
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2016-02-18
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