IPr*(2‑Np)An Exceedingly Bulky N‑Heterocyclic Carbene
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Does size matter? The bulkiest, yet still highly flexible, N-heterocyclic carbene to date is reported. Its imidazolium salt proved to be easily synthesized in only four steps on a 3.6 g scale. This new ligand was fully characterized and engaged in the formation of complexes with silver(I), copper(I), rhodium(I), and palladium(II).
创建时间：
2016-02-18
