Long-Term Operando NMR data on the Quantification of Li Plating on Graphite Anodes

Operando variable-temperature electrochemical solid-state ⁷Li nuclear magnetic resonance (NMR) spectroscopy is used to quantify Li plating (onset, plated amount, reversibility) in LiFePO4/graphite batteries cycled till 30% SOH at both 25°C and 45°C with three distinct electrolytes: (1) Base electrolyte (1M LiPF6 in EC:EMC 3:7); (2) BV electrolyte (Base + 2 vol% VC); and (3) BDF electrolyte (Base + 2 wt% LiDFOB).This dataset contains 6 opernado NMR measurements for each electrolyte and temperature condition listed above. Li plating quantified by NMR is summarized.