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Metal-Free Azaphosphaannulation of Phosphonamides through Intramolecular Oxidative C–N Bond Formation

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NIAID Data Ecosystem2026-03-08 收录
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We report an efficient metal-free azaphosphaannulation of a myriad of phosphonamides through intramolecular oxidative C–N bond formation using PhI­(OAc)2 and iodine in acetonitrile under air, thus leading to the formation of benzazaphosphol-3-one 1-oxides, which are novel phosphorus heterocyclic privileged structures.

创建时间:
2014-06-06
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