Convenient Access to Homo- and Heterobimetallic Alkoxo Hydridozinc Clusters of Formula [(HZnO<i>t</i>Bu)<sub>4</sub><sub>-</sub><i><sub>n</sub></i>(LiO<i>t</i>Bu)<i><sub>n</sub></i>] (<i>n</i> = 0, 1, 2, 3)
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A convenient and efficient route to the stable and soluble alkoxo hydridozinc clusters {[HZnOtBu]3[Li(thf)OtBu]}, {[HZnOtBu]2[Li(thf)OtBu]2}, and {[HZnOtBu][Li(thf)OtBu]3} is described by cluster core metathesis reactions between [HZnOtBu]4 and [LiOtBu] aggregates in THF solutions. They are the first examples of alkoxo hydridozinc clusters structurally characterized and consist of heterocubane cores.
创建时间：
2006-10-09
