Untangling Complex Redox Chemistry in Zeolitic Imidazolate Frameworks Using Fourier Transformed Alternating Current Voltammetry
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https://figshare.com/articles/dataset/Untangling_Complex_Redox_Chemistry_in_Zeolitic_Imidazolate_Frameworks_Using_Fourier_Transformed_Alternating_Current_Voltammetry/5414821
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资源简介：
Two zeolitic imidazolate
frameworks, ZIF-67 and ZIF-8, were interrogated
for their redox properties using Fourier transformed alternating current
voltammetry, which revealed that the 2-methylimidazolate ligand is
responsible for multiple redox transformations. Further insight was
gained by employing discrete tetrahedral complexes, [M(DMIM)4]2+ (DMIM = 1,2-dimethylimidazole, M = CoII or ZnII) which have similar structural motifs to ZIFs.
In this work we demonstrate a multidirectional approach that enables
the complex electrochemical behavior of ZIFs to be unraveled.
创建时间：
2017-08-03
