Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand
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https://figshare.com/articles/dataset/Synthesis_of_Tungsten_Imido_Alkylidene_Complexes_that_Contain_an_Electron_Withdrawing_Imido_Ligand/2041731
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资源简介：
Tungsten NArR alkylidene
complexes have been prepared
that contain the electron-withdrawing ArR groups 2,4,6-X3C6H2 (ArX3, X = Cl, Br),
2,6-Cl2-4-CF3C6H2 (ArCl2CF3), and 3,5-(CF3)2C6H3 (Ar(CF3)2). Reported complexes include W(NArR)2Cl2(dme) (dme = 1,2-dimethoxyethane),
W(NArR)2(CH2CMe3)2, W(NArR)(CHCMe3)(OTf)2(dme),
and W(NArR)(CHCMe3)(ODBMP)2 (DBMP
= 4-Me-2,6-(CHPh2)C6H2). The W(NArR)(CHCMe3)(ODBMP)2 complexes were explored
as initiators for the polymerization of 2,3-dicarbomethoxynorbornadiene
(DCMNBD).
创建时间：
2015-12-17
