The First Structurally Characterized Aluminum Compound with Two SH Groups: [LAl(SH)<sub>2</sub>] (L = N(Ar)C(Me)CHC(Me)N(Ar), Ar = 2,6-<i>i</i>-Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>) and the Catalytic Properties of the Sulfur P(NMe<sub>2</sub>)<sub>3</sub> System
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Surprisingly stable is the bis(hydrogen sulfide) of aluminum LAl(SH)2 with two terminal arranged SH groups. The insertion of sulfur into the Al−H bonds is catalyzed by SP(NMe2)3. A possible mechanism is discussed.
创建时间：
2016-08-18
