Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex
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https://figshare.com/articles/dataset/Oxidative_Group_Transfer_to_Co_I_Affords_a_Terminal_Co_III_Imido_Complex/3644187
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资源简介：
The synthesis of the first terminal imido complex of cobalt, [PhBP3]Co⋮N-p-tolyl, is reported. Its synthesis proceeds by oxidative group transfer from cobalt(I) upon addition of tolyl azide at room temperature. This species and a related η-diazoalkane adduct have been structurally characterized. The diamagnetic imido complex [PhBP3]Co⋮N-p-tolyl reacts with CO to liberate isocyanate and the cobalt(I) dicarbonyl complex [PhBP3]Co(CO)2.
创建时间：
2016-08-18
