Total Synthesis of (±)-Powelline and (±)-Buphanidrine
收藏NIAID Data Ecosystem2026-03-06 收录
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The total synthesis of (±)-powelline (13 linear steps in an overall yield of 6%) and (±)-buphanidrine (14 linear steps and a 6% overall yield) and has been achieved using a novel approach to the crinane skeleton. An organocatalytic oxidative coupling allowed direct construction of the key quaternary carbon-to-aryl bond in high yield allowing rapid access to the target alkaloids.
创建时间：
2010-03-19
