Gold-Catalyzed Reactivity Reversal of Indolizidinone-Tethered β‑Amino Allenes Controlled by the Stereochemistry
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https://figshare.com/articles/dataset/Gold_Catalyzed_Reactivity_Reversal_of_Indolizidinone_Tethered_Amino_Allenes_Controlled_by_the_Stereochemistry/2142688
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资源简介：
The controllable cyclization reaction
of indolizidinone-tethered
β-amino allenes has been achieved through gold catalysis. The
expected cycloisomerization of the syn-isomer sharply
contrasts to the unprecedented bis(azacyclization)–spirocyclization
sequence of the epimeric anti-isomer, offering highly
selective access to enantiopure fused and spiranic azapolycycles.
创建时间：
2016-02-13
