Computationally Guided Organometallic Chemistry: Preparation of the Heptacyclic Pyrazine Core of Ritterazine N
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https://figshare.com/articles/dataset/Computationally_Guided_Organometallic_Chemistry_Preparation_of_the_Heptacyclic_Pyrazine_Core_of_Ritterazine_N/3230191
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资源简介：
Diels−Alder cycloaddition of 10 followed by Wittig homologation and intramolecular diene cyclozirconation of the resulting triene under equilibrating conditions led to the tricyclic 6−6−5 ketone 5 with
high diastereocontrol. The derived α-azido ketone 16 cyclized efficiently to the heptacyclic pyrazine
core of ritterazine N.
创建时间：
2006-03-31
