Thermodynamic and kinetic parameters of R-2AP dimers H-atom donation to O<sub>2</sub>.

NIAID Data Ecosystem2026-03-10 收录

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Thermodynamic and kinetic parameters of R-2AP dimers H-atom donation to O2.

创建时间：

2018-12-20

Large Ground-State Entropy Changes for Hydrogen Atom Transfer Reactions of Iron Complexes

氢原子转移反应

热力学参数

Reported herein are the hydrogen atom transfer (HAT) reactions of two closely related dicationic iron tris(α-diimine) complexes. FeII(H2bip) (iron(II) tris[2,2‘-bi-1,4,5,6-tetrahydropyrimidine]diperch

NIAID Data Ecosystem80

Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reactions

氢原子转移反应

氧原子转移反应

Two new pentadentate {N5} donor ligands based on the N4Py (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine) framework have been synthesized, viz. [N-(1-methyl-2-benzimidazolyl)methyl-N

NIAID Data Ecosystem40

A Mononuclear Non-heme Manganese(III)–Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions

金属配合物催化

氢原子转移反应

A mononuclear non-heme Mn(III)–aqua complex, [(dpaq)MnIII(OH2)]2+ (1, dpaq = 2-[bis(pyridin-2-ylmethyl)]amino-N-quinolin-8-yl-acetamidate), is capable of conducting hydrogen atom transfer (HAT)

Figshare2018-10-02 更新10

TEMPO-Mediated Catalysis of the Sterically Hindered Hydrogen Atom Transfer Reaction between (C5Ph5)Cr(CO)3H and a Trityl Radical

化学催化动力学

氢原子转移反应

We have demonstrated the ability of TEMPO to catalyze H· transfer from (C5Ph5)Cr(CO)3H to a trityl radical (tris(p-tert-butylphenyl)methyl radical). We have measured the rate constant and activati

Figshare2019-01-28 更新40

Ruthenium(II) Porphyrin Quinoid Carbene Complexes: Synthesis, Crystal Structure, and Reactivity toward Carbene Transfer and Hydrogen Atom Transfer Reactions

金属卡宾配合物催化

氢原子转移反应

Reactivity study of novel metal carbene complexes can offer new opportunities in catalytic carbene transfer reactions as well as in other synthetic protocols. Metal complexes with quinoid carbene (QC)

NIAID Data Ecosystem30

Thermodynamic and kinetic parameters of R-2AP dimers H-atom donation to O<sub>2</sub>.

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