Iridium-Catalyzed Borylation of Pyrene: Irreversibility and the Influence of Ligand on Selectivity
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https://figshare.com/articles/dataset/Iridium_Catalyzed_Borylation_of_Pyrene_Irreversibility_and_the_Influence_of_Ligand_on_Selectivity/2219863
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资源简介：
The iridium-catalyzed borylation
of pyrene, using 4,4′-dimethyl-2,2′-bipyridine
as the ligand, in the presence of t-BuOK, gave a
mixture of 2,4,7,9-tetrakis(Bpin)pyrene (c4) and its 2,4,7,10-isomer (m4) in a 2.2:1 ratio, and
the selectivity of the Ir-catalyzed borylation of pyrene is kinetically
determined and can be influenced to some extent by the nature of the
ligand.
创建时间：
2015-01-02
