Two-Dimensional Homometallic- to a Three Dimensional Heterometallic Coordination Polymer: A Metalloligand Approach
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https://figshare.com/articles/dataset/Two_Dimensional_Homometallic_to_a_Three_Dimensional_Heterometallic_Coordination_Polymer_A_Metalloligand_Approach/2326525
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资源简介：
A metalloligand
type of synthetic route has been followed to generate
a novel heterometallic three-dimensional (3D)-coordination polymer
containing Cu(II) and trimethyltin as nodes. The first step of this
synthetic path consisted of the preparation of a two-dimensional-coordination
polymer of Cu(II), [Cu(μ-LH)2]n (1) (LH2 = pyridine-2,5-dicarboxylic
acid). The reaction of in situ generated 1 with Me3SnCl afforded the heterometallic 3D-coordination polymer,
[Cu(Me3Sn)2(μ-L)2]n (2). The latter is a 4,4-connected
polymer with a sqc topology. This 3D-framework contains a paddle-wheel-shaped
core comprised of two heterometallic (CuII/SnIV) macrocycles.
创建时间：
2016-02-18
