Chiral NHC-Catalyzed Oxodiene Diels−Alder Reactions with α-Chloroaldehyde Bisulfite Salts
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下载链接:
https://figshare.com/articles/dataset/Chiral_NHC_Catalyzed_Oxodiene_Diels_Alder_Reactions_with_Chloroaldehyde_Bisulfite_Salts/2916703
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资源简介:
α-Chloroaldehyde bisulfite adducts were successfully
employed in chiral NHC-catalyzed hetero-Diels−Alder reactions
with various oxodienes under biphasic reaction conditions with high
levels of enantioselectivity. This new protocol makes possible enantioselective
additions from commercially available chloroacetaldehyde sodium bisulfite
and demonstrates that this unique class of catalysts readily tolerates
aqueous conditions.
创建时间:
2016-02-27



