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Cobalt(II) Coordination Polymer Exhibiting Single-Ion-Magnet-Type Field-Induced Slow Relaxation Behavior

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Figshare2016-02-13 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cobalt_II_Coordination_Polymer_Exhibiting_Single_Ion_Magnet_Type_Field_Induced_Slow_Relaxation_Behavior/2174989
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A one-dimensional cobalt­(II) coordination polymer, [Co­(btm)2(SCN)2·H2O]n [btm = bis­(1H-1,2,4-triazol-1-yl)­methane], was synthesized and magnetically characterized. The isolated slightly distorted octahedral CoII ion displays field-induced slow relaxation with a big positive axial and a negative rhombic magnetic anisotropy (D = 93.9 cm–1 and E = −10.5 cm–1), and the anisotropy energy barrier is 45.4 K.
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2016-02-13
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