Cobalt(II) Coordination Polymer Exhibiting Single-Ion-Magnet-Type Field-Induced Slow Relaxation Behavior
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A one-dimensional cobalt(II) coordination polymer, [Co(btm)2(SCN)2·H2O]n [btm = bis(1H-1,2,4-triazol-1-yl)methane], was synthesized and magnetically characterized. The isolated slightly distorted octahedral CoII ion displays field-induced slow relaxation with a big positive axial and a negative rhombic magnetic anisotropy (D = 93.9 cm–1 and E = −10.5 cm–1), and the anisotropy energy barrier is 45.4 K.
创建时间:
2016-02-13



