Chiral Induction in Phenanthroline-Derived Oligoamide Foldamers: An Acid- and Base-Controllable Switch in Helical Molecular Strands
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A series of phenanthroline-derived oligoamides bearing a chiral (R)-phenethylamino end group were synthesized that displayed chiral helical induction and subsequently formed one-hand helical foldamers in solution. Moreover, an acid- and base-controllable switch in the helical molecular strands was observed, which has been demonstrated by NMR, UV−vis, and circular dichroism spectroscopy.
创建时间：
2016-06-03
