Synthesis and Ruthenium Coordination Complexes of the Chelating Phosphine Phosphonium-1-indenylide 1,1-Bis(diphenylphosphino)methane-1-indenylide,1‑C9H6Ph2PCH2PPh2
收藏Figshare2016-02-20 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_and_Ruthenium_Coordination_Complexes_of_the_Chelating_Phosphine_Phosphonium_1_indenylide_1_1_Bis_diphenylphosphino_methane_1_indenylide_1_C_sub_9_sub_H_sub_6_sub_Ph_sub_2_sub_PCH_sub_2_sub_PPh_sub_2_sub_/2480326
下载链接
链接失效反馈官方服务：
资源简介：
Bis(diphenylphosphino)methane-1-indenylide, 1-C9H6PPh2CH2PPh2 (1-C9H6dppm, I), has been synthesized and characterized by NMR spectroscopy and X-ray crystallography. I reacts with [CpRu(MeCN)3]PF6 to form the conventional sandwich complex [CpRu(η5-I)]PF6 (II), which contains a dangling −PPh2 group. Complex II isomerizes to the 18-electron species IIIc, in which the dangling −PPh2 group coordinates to the ruthenium, forcing slippage of the five-membered ring to an unanticipated 1,9,8-η3-exo mode of coordination.
创建时间：
2016-02-20
