Design, Synthesis, and Evaluation of a Helicenoidal DMAP Lewis Base Catalyst
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https://figshare.com/articles/dataset/Design_Synthesis_and_Evaluation_of_a_Helicenoidal_DMAP_Lewis_Base_Catalyst/2687236
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资源简介：
The design, synthesis, and study of a helical dialkylaminopyridine
Lewis base catalyst is reported. Helical DMAP analogue 4 is based upon a helicenoid structure and displays good to excellent
levels of selectivity (S ≤ 116) in the kinetic
resolution of chiral secondary alcohols. Catalyst 4 displays
excellent reactivity with exceptionally low loadings of 0.05 mol %
effecting practical levels of selectivity in kinetic resolutions.
创建时间：
2016-02-23
