Diels–Alder Reaction of Tropones with Arynes: Synthesis of Functionalized Benzobicyclo[3.2.2]nonatrienones
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Diels_Alder_Reaction_of_Tropones_with_Arynes_Synthesis_of_Functionalized_Benzobicyclo_3_2_2_nonatrienones/2291926
下载链接
链接失效反馈官方服务：
资源简介：
A new procedure for the mild, practical,
and scalable Diels–Alder
reaction of tropones with arynes is reported. Differently substituted
tropones undergo selective [4 + 2] cycloaddition with arynes generated
in situ by the fluoride-induced 1,2-elimination of 2-(trimethylsilyl)aryl
triflates, allowing the formation of functionalized benzobicyclo[3.2.2]nonatrienone
derivatives in moderate to good yields. In addition, the photophysical
properties of the cycloadducts are presented.
创建时间：
2016-02-17
