Bis(m‑terphenyl)silanes

Figshare2016-02-16 更新2026-04-29 收录

有机硅化学

位阻化合物合成

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The synthesis and full characterization of the first bis(m-terphenyl)silanes, namely, (2,6-Mes2C6H3)2SiF2, (2,6-Mes2C6H3)2SiHF, and (2,6-Mes2C6H3)2SiH2, is reported.

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2016-02-16

Solution and X-ray Structure of Triethylsilylmethyl-Substituted Tropylium Cation

有机硅化学

X射线晶体学

The β-silyl tropylium cation 9 has been successfully generated in the presence of the noncoordinating counterion tetrakis(pentafluorophenyl)borate in benzene and toluene. The 13C and 29Si NMR spectra

NIAID Data Ecosystem60

Synthesis of an NHC-Coordinated Dialkyldisilavinylidene and Its Oxidation Providing a Silicon Analog of an Acetolactone

有机硅化学

配位化学

Although isolable silicon analogs of acetylene have been extensively studied, the silicon analogs of vinylidene, which is a short-lived isomer of acetylene, remain scarce. Herein, we report isolable N

NIAID Data Ecosystem50

Reactivity Studies of a Disilene with N2O and Elemental Sulfur

有机硅化学

反应机理

In a previous contribution, we have reported on a convenient and high yield synthesis of the disilene trans-[(TMS)2N(η1-Me5C5)SiSi(η1-Me5C5)N(TMS)2] (2). Herein, we show the reactions of 2 with N2O a

Figshare2016-02-22 更新20

Dispersion-Energy-Driven Wagner–Meerwein Rearrangements in Oligosilanes

有机硅化学

分子重排

The installation of structural complex oligosilanes from linear starting materials by Lewis acid induced skeletal rearrangement reactions was studied under stable ion conditions. The produced cations

NIAID Data Ecosystem60

Silver-Catalyzed Silacyclopropenation of 1-Heteroatom-Substituted Alkynes and Subsequent Rearrangement Reactions

有机硅化学

催化反应机理

Silver phosphate-catalyzed silylene transfer from silacyclopropane 1 to 1-heteroatom-substituted alkynes resulted in alkoxy-, amino-, and alkylthiolate-substituted silacyclopropenes. Silver-catalyzed

NIAID Data Ecosystem40

Bis(m‑terphenyl)silanes

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