Series of Metal Organic Frameworks Assembled from Ln(III), Na(I), and Chiral Flexible-Achiral Rigid Dicarboxylates Exhibiting Tunable UV–vis–IR Light Emission
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https://figshare.com/articles/dataset/Series_of_Metal_Organic_Frameworks_Assembled_from_Ln_III_Na_I_and_Chiral_Flexible_Achiral_Rigid_Dicarboxylates_Exhibiting_Tunable_UV_vis_IR_Light_Emission/2553106
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资源简介：
Two series of isoreticular chiral metal–organic
frameworks
assembled from Ln(III) (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb), Na(I),
and chiral flexible-achiral rigid dicarboxylate ligands, formulated
as [NaLn(Tart)(BDC)(H2O)2] (S1)
and [NaLn(Tart)(biBDC)(H2O)2] (S2) (H2Tart = tartaric acid; H2BDC = terephthalic
acid; H2biBDC = biphenyl-4,4′-dicarboxylic acid),
were obtained as single phases under hydrothermal conditions. The
compounds have been studied by single-crystal and powder X-ray diffraction,
thermal analyses (TG-MS and DSC), vibrational spectroscopy (FTIR),
scanning electron microscopy (SEM-EDX), elemental analysis, and X-ray
thermodiffractometry. The catalytic activity has been also investigated.
The photoluminescence properties of selected compounds have been investigated,
exhibiting room temperature tunable UV–vis–IR light
emission.
创建时间：
2012-02-06
