Materials Data on TeC4(ClF3)2 by Materials Project

(CF2)2C2Te(ClF)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight difluoromethane molecules and four C2Te(ClF)2 clusters. In each C2Te(ClF)2 cluster, C+2.50+ is bonded in a distorted single-bond geometry to one Te2- and one F1- atom. The C–Te bond length is 2.14 Å. The C–F bond length is 1.35 Å. Te2- is bonded in a distorted rectangular see-saw-like geometry to two equivalent C+2.50+ and two equivalent Cl1- atoms. Both Te–Cl bond lengths are 2.53 Å. Cl1- is bonded in a distorted single-bond geometry to one Te2- atom. F1- is bonded in a single-bond geometry to one C+2.50+ atom.