A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound
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https://figshare.com/articles/dataset/A_Dimethylgallium_Boryl_Complex_and_Its_Methyllithium_Addition_Compound/2330152
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资源简介：
The three-coordinate complex Me2Ga[B(NArCH)2] (Ar = C6H3iPr2-2,6) is accessible via a tandem Lewis acid–base metathesis protocol employing (THF)2Li[B(NArCH)2] and GaMe3. It features
a very
short Ga–B bond of 2.067(3) Å, which was further investigated
by DFT calculations and the analysis of the electron density. Reaction
of MeLi with Me2Ga[B(NArCH)2] forms tetrameric
[LiMe3Ga{B(NArCH)2}]4 with a “nanowheel”
structure.
创建时间：
2014-01-22
