A Formal Metal-Free N‑Arylation via the Schmidt Reaction of Aromatic Aldehydes with an Azido Amine
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https://figshare.com/articles/dataset/A_Formal_Metal_Free_i_N_i_Arylation_via_the_Schmidt_Reaction_of_Aromatic_Aldehydes_with_an_Azido_Amine/2438953
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A formal metal-free N-arylation of aromatic aldehydes with 3-azido-N-tosylpropan-1-amine through the Schmidt process was realized in the presence of acids. TfOH was found to be a good promoter, and the exclusive 1,2-aryl migration was observed. Furthermore, the conversion of an aliphatic aldehyde to the N,N-disubstituted formamide was achieved in excellent yield.
创建时间：
2016-02-19
