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Metal Nitrate Mediated Regioselective Nitration of BN-Substituted Arenes

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https://figshare.com/articles/dataset/Metal_Nitrate_Mediated_Regioselective_Nitration_of_BN-Substituted_Arenes/4892732
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资源简介:
A regioselective nitration of BN-substituted arene compounds has been successfully developed. The first examples of BN-nitroarenes have been synthesized and structurally characterized by X-ray diffraction analysis. Photophysical studies of these novel compounds reveal an effective π conjugation between the nitro group and 1,2-azaborine moiety in the solution phase. A plausible mechanism for this nitration reaction is proposed.
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2017-04-20
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