Transition-Metal Controlled Diastereodivergent Radical Cyclization/Azidation Cascade of 1,7-Enynes
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https://figshare.com/articles/dataset/Transition_Metal_Controlled_Diastereodivergent_Radical_Cyclization_Azidation_Cascade_of_1_7_Enynes/3249472
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资源简介：
A strategy
for achieving diastereodivergent azidations of enynes
has been developed, employing azide transfer from the M–N3 complex to alkyl radicals. Following this concept, the diastereoselectivity
has been switched by modulating the transition metals and the ligands.
The Mn(III)-mediated radical cyclization/azidation cascade of 1,7-enynes
afforded trans-fused pyrrolo[3,4-c]quinolinones, whereas the Cu(II)/bipyridine system gave cis-products.
创建时间：
2016-05-16
