Cp*Rh-Based Heterometallic Metallarectangles: Size-Dependent Borromean Link Structures and Catalytic Acyl Transfer
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https://figshare.com/articles/dataset/Cp_Rh_Based_Heterometallic_Metallarectangles_Size_Dependent_Borromean_Link_Structures_and_Catalytic_Acyl_Transfer/2409664
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资源简介：
A series of Cp*Rh-based functional
metallarectangles have been
synthesized from metallaligands. Enlargement of one linker leads to
the isolation of two novel Borromean link architectures. All these
complexes are intact in solution, as evident from ESI-MS spectroscopic
analysis. Arising from the combination of open Cu centers and favorable
cavity space, {(Cp*Rh)4(bpe)2[Cu(opba)·2MeOH]2}4(OTf)·6MeOH shows extraordinary catalytic
abilities with high efficiency and wide substrate selectivity in the
acyl-transfer reaction.
创建时间：
2016-02-19
