Studies on the Photochemical Rearrangements of Enantiomerically Pure, Polysubstituted, and Variously Annulated Bicyclo[2.2.2]octenones
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https://figshare.com/articles/dataset/Studies_on_the_Photochemical_Rearrangements_of_Enantiomerically_Pure_Polysubstituted_and_Variously_Annulated_Bicyclo_2_2_2_octenones/5226433
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资源简介：
A series
of enantiomerically pure bicyclo[2.2.2]octenones, including
the lactone-annulated system 26, has been prepared by
engaging derivatives of an enzymatically derived and homochiral cis-1,2-dihydrocatechol in inter- or intra-molecular Diels–Alder
reactions. Systems such as 26 readily participate in
photochemically promoted oxa-di-π-methane rearrangement or 1,3-acyl
migration processes to give products such as diquinane 34 or mixtures of cyclobutanone 36 and cyclopropane 38, respectively.
创建时间：
2017-07-20
