A New Form of Triple-Stranded Helicate Found in Uranyl Complexes of Aliphatic α,ω-Dicarboxylates
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https://figshare.com/articles/dataset/A_New_Form_of_Triple_Stranded_Helicate_Found_in_Uranyl_Complexes_of_Aliphatic_Dicarboxylates/2109049
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资源简介：
The
reaction of uranyl ions with azelaic or dodecanedioic acids under
solvohydrothermal conditions leads to crystallization of anionic dinuclear
cage compounds with [M(bipy/phen)3]2+ counterions
(M = 3d-block cation), while the smaller suberic acid yields heterometallic
metallacycles. Complexes with the longer aliphatic chains are the
first triple-stranded helicates reported in actinide chemistry.
创建时间：
2016-11-05
