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1-D Coordination Polymers Made of Asymmetrical Copper Nitroxide Bis-Chelates

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/1_D_Coordination_Polymers_Made_of_Asymmetrical_Copper_Nitroxide_Bis_Chelates/3340408
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Mixed-ligand copper nitroxide complexes Cu(ptfa)L (ptfa = pivaloyltrifluoroacetonato, L = nitrile-substituted nitroxide enaminoketone) have been synthesized and characterized structurally and magnetically. The complexes are 1-D nitrile-bound coordination polymers in contrast to 2-D and 3-D Cu(hfac)L (hfac = hexafluoroacetylacetonato) studied earlier. The magnetic dimensionality of Cu(ptfa)L is zero, and weak ferromagnetic exchange of an intramolecular nature is observed.
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2016-05-07
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