Amine-Ligated Approach for the Synthesis of Extra-Large-Pore Zinc Phosphites with qtz‑h and bnn Topologies
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https://figshare.com/articles/dataset/Amine_Ligated_Approach_for_the_Synthesis_of_Extra_Large_Pore_Zinc_Phosphites_with_qtz_h_and_bnn_Topologies/3145765
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资源简介：
Presented here are two open-framework
zinc phosphites, namely, Zn(dabco)0.5(HPO3)
(SCU-18) and Zn4(Hdabco)2(CH3COO)2(HPO3)4 (SCU-20), where dabco = 1,4-diazabicyclo[2.2.2]octane.
SCU-18 features a rare 3-connected inorganic skeleton with a chiral
qtz-h topology. It contains 18-membered-ring (18 MR) channels displaying
porosity and second-harmonic-generation response. SCU-20 has a bnn
topology containing large 20 MR channels that shows a strong blue
emission as a result of excitation at 375 nm.
创建时间：
2016-04-12
