Synthesis and Structure of Cationic Phosphine Gold(I) Enol Ether Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Cationic_Phosphine_Gold_I_Enol_Ether_Complexes/2470468
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资源简介:
Cationic {[(t-Bu)2(o-biphenyl)P]Au(enol ether)}+SbF6– and {[(t-Bu)3P]Au(enol
ether)}+SbF6– complexes were
isolated and characterized by NMR spectroscopy and X-ray crystallography.
For three of the four complexes characterized in the solid state,
gold coordinates to the electron-rich bond in a η1 fashion, while a 2,3-dihydrofuran complex displays η2 coordination.
创建时间:
2012-11-12



