Self-Addition of a Sterically Hindered Alkynylselenolate
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https://figshare.com/articles/dataset/Self-Addition_of_a_Sterically_Hindered_Alkynylselenolate/3746739
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资源简介：
The unprecedented formation of a complex macrocyclic selenium−carbon ring system, which is initiated by the action of coordinating reagents
upon a sterically hindered alkynylselenolate, has been observed. The crystal structure of the product could be obtained and shows a rigid
tricyclic arrangement consisting only of selenium and sp2-hybridized carbon atoms. This reactivity stands in contrast to the corresponding
unsubstituted alkynylselenolates and is an example where a bulky substituent destabilizes an adjacent unsaturated π-system.
创建时间：
2016-08-20
