Restoring Symmetry and Enhancing Exchange via Chiral Molecular-Magnetic Hexagons

Modified behaviors of molecules, designed for device
or energy
applications, can occur due to lattice-molecule incompatibilities
in point-group symmetries (PGS), long-range interactions between neighboring
molecules, or lattice-molecule charge transfer. Such sensitivities
are a prerequisite for the use of quantum molecules as devices, but
removing certain broken symmetries is desirable from the standpoint
of simplifying their behaviors. Here, we demonstrate symmetry restoration
to molecular-magnetic lattices and show that it leads to strengthened
exchange coupling due to dipolar electrostatic interactions between
neighboring molecules and due to manifestations of an earlier identification
of a spin-sensitive slightly mobile electron by et al. [Hooshmand, Z. Phys. Rev. B 2021, 104, 134411]. Starting with a broken symmetry molecular
magnet of current interest, we demonstrate a more robust structure
composed of six molecular magnets on an h-BN-like
surface. The broken point-group symmetry is healed by constructing
interpenetrating equilateral triangular structures that are appropriately
ratcheted to preserve 3-fold rotational symmetry and inversion symmetry.