Layered Assemblies of a Dialuminum-Substituted Silicotungstate Trimer and the Reversible Interlayer Cation-Exchange Properties
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https://figshare.com/articles/dataset/Layered_Assemblies_of_a_Dialuminum_Substituted_Silicotungstate_Trimer_and_the_Reversible_Interlayer_Cation_Exchange_Properties/2570299
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资源简介：
Two polyoxometalate assemblies, TBA9[{γ-H2SiW10O36Al2(μ-OH)2(μ-OH)}3] (1; TBA = tetra-n-butylammonium) and TBA6Li3[{γ-H2SiW10O36Al2(μ-OH)2(μ-OH)}3]·18H2O (2), were synthesized by trimerization of a dialuminum-substituted
silicotungstate monomer. Both 1 and 2 possessed
a layered structure composed of a basal sheet unit [TBA3{γ-H2SiW10O36Al2(μ-OH)2(μ-OH)}3]6– and interlayer cations. The interconversion between 1 and 2 reversibly took place through interlayer cation
exchange.
创建时间：
2011-12-19
