Phosphepines: Convenient Access to Phosphinidene Complexes
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https://figshare.com/articles/dataset/Phosphepines_Convenient_Access_to_Phosphinidene_Complexes/3289378
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资源简介：
Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75−80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.
创建时间：
2016-05-06
