Palladium-Catalyzed Chemoselective Synthesis of 2‑Aminocinnamyl Esters via Sequential Amination and Olefination of Aryl Iodides
收藏Figshare2020-09-28 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Palladium-Catalyzed_Chemoselective_Synthesis_of_2_Aminocinnamyl_Esters_via_Sequential_Amination_and_Olefination_of_Aryl_Iodides/13058160
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We report a highly chemoselective palladium-catalyzed Catellani-type amination of aryl iodides terminated by the Heck reaction using allylic esters as terminating reagents. 2-Aminocinnamyl esters were formed exclusively via β-H elimination rather than β-OAc elimination without the assistance of a silver salt. This protocol represents a useful extension of Catellani-type transformations.
创建时间：
2020-09-28
