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Synthesis of Quinoxaline Derivatives via Tandem Oxidative Azidation/Cyclization Reaction of N‑Arylenamines

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Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Quinoxaline_Derivatives_via_Tandem_Oxidative_Azidation_Cyclization_Reaction_of_i_N_i_Arylenamines/2078707
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A new method was developed for the synthesis of quinoxalines. This method employs N-arylenamines and TMSN3 as the starting materials and implements two oxidative C–N bond-forming processes in a tandem pattern by using (diacetoxyiodo)­benzene as the common oxidant. The present reaction conditions are mild and simple and thus are useful in practical synthesis.
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2016-02-12
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