Fluorine-Induced Gradient Electric Field in Mesoporous Covalent Organic Frameworks for Efficient Separation of Polarized Perfluorinated Gases

The dataset includes raw data for adsorption isotherms, ideal adsorbed solution theory (IAST) calculations, breakthrough experiments, and structural characterizations such as PXRD, N₂ sorption isotherms, and optimized atomic coordinates of the covalent organic frameworks. These data are intended to support the main findings of the manuscript and to promote transparency and reproducibility.