An Anionic Heptacopper(II) Oxo-Cluster {CuII7} with an S = 7/2 Ground State
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https://figshare.com/articles/dataset/An_Anionic_Heptacopper_II_Oxo_Cluster_Cu_sup_II_sup_sub_7_sub_with_an_i_S_i_7_2_Ground_State/2086510
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An anionic heptacopper(II) oxo-cluster {Cu7} was obtained from a simple reaction in aqueous solution without heating. In a similar reaction, another cage compound {Sb12} with an encapsulated {Cu2} core was produced, implying the structural versatility of copper(II)-oxide assemblies constructed from potassium antimonyl tartrate as the ligand in aqueous solution. The ferromagnetic S = 7/2 ground state of {Cu7} is confirmed by magnetization measurements.
创建时间:
2016-02-12



