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Facile Access to Tetravalent Cerium Compounds: One-Electron Oxidation Using Iodine(III) Reagents

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Facile_Access_to_Tetravalent_Cerium_Compounds_One_Electron_Oxidation_Using_Iodine_III_Reagents/2722705
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资源简介:
Readily accessible and easy-to-use phenyliodine(III) dichloride, PhICl2, has been established as an innovative and superior reagent for the one-electron oxidation of cerium(III) complexes, comprising amide, amidinate, and cyclopentadienyl derivatives. Its use allowed the successful synthesis and structural characterization of the first members of three new classes of chloro-functionalized (organo)cerium(IV) compounds, including the long sought-after Cp3CeCl.
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2010-10-13
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