Solvent-Dependent Networking of O<sub>2</sub>S<sub>2</sub>-Macrocycle with Silver Perchlorate into One- and Two-Dimensional Coordination Polymers
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The solvent-dependent double-stranded one-dimensional (1-D) coordination polymer [Ag2L2(ClO4)2]n (1) and another 1-D polymer {[Ag2L2(CH3CN)]·2ClO4}n (2a) with the shape of a cut of tube along the long axis were obtained in the reactions of a 16-membered O2S2-macrocycle L with silver(I) perchlorate in DCM/MeOH and CH3CN, respectively. Time-dependent crystallization experiments unambiguously show that 2a is a kinetic product and transforms into a thermodynamically more stable [AgLClO4]n (2b) with a two-dimensional square-grid structure.
创建时间：
2010-03-03
