A Homologous Series of Cobalt, Rhodium, and Iridium Metalloradicals
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/A_Homologous_Series_of_Cobalt_Rhodium_and_Iridium_Metalloradicals/2567173
下载链接
链接失效反馈官方服务：
资源简介：
We herein present a series of d7 trimethylphosphine
complexes of group 9 metals that are chelated by the tripodal tetradentate
tris(phosphino)silyl ligand [SiPiPr3]H ([SiPiPr3] = (2-iPr2PC6H4)3Si–). Both electron paramagnetic resonance (EPR) simulations
and density functional theory (DFT) calculations indicate largely
metalloradical character. These complexes provide a rare opportunity
to compare the properties between the low-valent metalloradicals of
the second- and third-row transition metals with the corresponding
first-row analogues.
创建时间：
2012-01-02
